The explanation I seem to remember hearing from somebody, to explain that the pressure near the rim would be lower than near the middle, was supposed to apply to the case where a dome enclosed the Earth and thus the air column above an observer near the rim would be much shorter than the air column in the middle.
However, this doesn't mean the pressure would be less: as skeptical scientist mentioned, if the pressure there were less, then the air in the middle would press outwards until the pressure were equalized at any given altitude.
Just imagine a conical basin filled with water. The pressure will, as always, only be a function of depth: if somehow the pressure in the lower corner decreased, the rest of the water would sink and repressurize the water in the corner.