You were the one confusing atoms, electrons, and molecules, so it is quite obvious that you are a product of the American educational system.
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Care to explain how the nucleus of an atom stores the energy of a photon, or how a molecule stores energy without interaction of its constituent components, namely atoms? Your first post seemed to be really confused about the subject, and that was the point I was making. I also noticed you had no answers for him either, while I at least was trying to pint him in the proper direction.
I don't actually know the answer to his question, so I made an educated guess. Certain classes of solids have lattice structures which would, I expect, be perturbed by exciting an electron to a higher energy state, increasing the size of an atom or ion. Your post didn't point him in the proper direction at all; you simply stated that solids use the same mechanism of absorbing and transmissing light energy as gas without then elaborating as to how the difference in structure would alter the emission spectrum.
Wow, you are way off. When an electron absorbs a photon, it doesnt really make a huge change in "orbit", but it does make a huge change in energy. Any positional change in the cloud is negligible, and far to tiny to cause any change in the structure of any lattice. You are thinking of it as changing its orbit height, which is a primitive way of looking at it to teach valence to middle schoolers.
As for re-emmison spectra:
When electrons in an atom get excited, they jump to higher energy levels. In order for them to do this, they must absorb energy. However, when electrons "calm down", they drop back down and thus release emit energy in the form of photons (the quanta of light). This emission of energy is the light that we see. The color of the light we see depends on the distance the electron drops--the longer the drop, the higher the energy.